Cobalt(II)–catalyzed C8 H alkoxylation of 1-naphthylamine derivatives with alcohols

Correction: Regioselective C8-metalation of N-phosphine tethered adenine derivatives via C8-H activation.

Correction for 'Regioselective C8-metalation of N-phosphine tethered adenine derivatives via C8-H activation' by D. Brackemeyer et al., Dalton Trans., 2017, DOI: 10.1039/c7dt00682a.

Regioselective C8-metalation of N-phosphine tethered adenine derivatives via C8-H activation.

Two new adenine derivatives bearing a N-methylene (1) or N-ethylene (2) tethered diphenylphosphine group have been reacted with [MIIICl2Cp*]2 (M = Ir, Rh) or [RuIIClCp*]4. The formation of Werner-type phosphine complexes [3]-[6] and upon heating their subsequent rearrangement into complexes bearing an NH,NR-NHC^PRPh2 chelate ligand in [7]Cl (M = Ir) and [8] (M = Ru) have been observed.

Cytotoxic and Antifungal Activities of Diverse α-Naphthylamine Derivatives

Diverse α-naphthylamine derivatives were easily prepared from corresponding aldimines derived from commercially available α-naphthaldehyde and anilines or isomeric pyridinecarboxyaldehydes and α-naphthylamine. The secondary amines obtained were tested as possible antifungal and cytotoxic agents. The diverse N-aryl-N-[1-(1-naphthyl)but-3-enyl]amines obtained were active (IC(50) < 10 μg/mL) again...

Electrocatalytic multicomponent assembling of aldehydes, dimedone and 1-naphthylamine for synthesis of novel tetrahydrobenzo[c]acridin-8(7H)-one derivatives

An efficient and convenient synthesis of novel tetrahydrobenzo[c]acridin-8(7H)-one derivatives is described using the electrogenerated anion of acetonitriles as the base in the presence of tetrabutylammonium fluoride as an effective supporting electrolyte in a one-pot, three-component condensation of aromatic aldehyde, dimedone and 1-naphthyl amine. The reaction is carried out in an undivided c...

Rings of functions with integer derivatives at x=1